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chief  (chiefs plural )
1  n-count The chief of an organization is the person who is in charge of it. 
...a commission appointed by the police chief.  
2  n-count; n-title The chief of a tribe is its leader. 
...Sitting Bull, chief of the Sioux tribes of the Great Plains.  
3  adj Chief is used in the job titles of the most senior worker or workers of a particular kind in an organization.  (=head) 
...the chief test pilot.  
4  adj The chief cause, part, or member of something is the most important one.  (=main, principal) 
Financial stress is well established as a chief reason for divorce...  
Chief Constable   (Chief Constables plural )A Chief Constable is the officer who is in charge of the police force in a particular county or area in Britain.  n-count; n-title 
chief executive officer   (chief executive officers plural )The chief executive officer of a company is the person who has overall responsibility for the management of that company. The abbreviation  CEO is often used.  (BUSINESS)  n-count 
Chief Justice   (Chief Justices plural )A Chief Justice is the most important judge of a court of law, especially a supreme court.  n-count; n-title 
Chief of Staff   (Chiefs of Staff plural )The Chiefs of Staff are the highest-ranking officers of each service of the armed forces.  n-count 
commander-in-chief   (commanders-in-chief plural )A commander-in-chief is an officer in charge of all the forces in a particular area.  n-count; n-title 
He was to be the commander-in-chief of the armed forces.